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Article of the Week

- The New Age of Waterborne Soft-Touch Coatings
Two-component (2K) polyurethane (PUR) soft-touch coatings have been used to coat plastics in the automotive industry for over a decade. Due to the inherent traits of polyurethanes, the coating formulations exhibit high scratch and abrasion resistance while maintaining low gloss. VOC regulations have guided a shift in chemistry for soft-touch coatings toward waterborne. Soft-touch coatings are now obtainable with low VOC, resulting in minimal fogging of the automobile windshield...

Most Popular Articles

- Organoclays: Additional possibilities offered to formulators thanks to new clay sources
Organoclays have long been used as rheological modifiers for solvent and oil based systems requiring pigment suspension and other thixotropic properties associated with the paint and ink markets...

- Crystallinity of Coatings Based on Polyvinylidene Fluoride
Many thermoplastic polymers are semi-crystalline; that is, they consist of amorphous regions and crystalline regions. In the amorphous regions, the polymer chains exist in a random pattern; in the crystalline regions, the polymer chains are in a regular, periodic pattern. The degree of crystallinity, and the size and physical arrangement of the crystallites, have a significant effect on the physical and mechanical properties of the polymer - and on organic coatings based on these polymers. Polyvinylidene fluoride (PVDF) is a thermoplastic, semi-crystalline polymer. Therefore, the properties of coatings based on PVDF, such as HYLAR ® 5000, are affected by the degree of crystallinity...

- Beyond the Zahn Cup
The standard coatings method for reading batch viscosity usually involves a Zahn or Efflux cup (Figure 1). This tried and true method involves testing for kinematic viscosity by dipping the cup into the batch and filling it with material. The user then draws the cup out of the material. When the cup breaks the surface, a stop watch is used to time the flow out of the hole in the bottom of the cup until the cup is empty. From this method, kinematic viscosity is then computed...

- 2-Component Polyurethane Topcoats
Polyurethane coatings are used today as architectural coatings, product finishes, automotive coatings and industrial maintenance coatings, making them among the most versatile coating types available. Polyurethane topcoats were introduced to the industrial maintenance and marine market in the mid-1970s as part of a corrosion protection system. The topcoat provides excellent weathering properties, i.e., good gloss retention and non-yellowing characteristics upon exposure to sunlight. When used in a basecoat/clearcoat combination, the weathering performance has been reported to be outstanding. They can also be formulated to provide good abrasion resistance, hydrolytic stability and resistance to a variety of solvents and chemicals. Polyurethane topcoats have evolved over the years into a coating technology that can be formulated to give low-VOC coatings, productivity-enhancing coatings, and long-lasting, cost-effective coatings...

- Novel High-Solids Systems Based On Silicone-Epoxy Resins
Corrosion protection for industrial, industrial maintenance and marine markets can be an expensive and overwhelming task. Protecting objects such as oil platforms, bridges, storage tanks, steel structures, concrete walls and floors, and ship decks from corrosion is labor-intensive, with high material costs. Still, one of the best methods for fighting corrosion is the use of protective coatings.

- Go Green - Online Training Reduces Your Company's Carbon Footprint!
It is the duty of all responsible chemical companies to find ways to reduce their carbon footprint as much as possible. In many cases this is easier said than done, but when it comes to training staff there is a simple solution - online training...

- New Anti-Fingerprint Coatings
Achieving oil and water repellency on surfaces is easily obtained with the use of fluoroalkyl-modified silanes. While perfluoroalkyl-modified silanes exhibit high static and advancing water and oil contact angles, their low receding contact angles mean the oil and water will not readily slide over the treated surface. The resulting effect of these characteristics yields a surface that is both easy to clean and stays clean longer. Ultimately, modified perfluoropolyether silanes give high static and advancing water and oil contact angles as well as high receding contact angles resulting in a very low sliding angle. The influence of structure modification of the silane and the perfluoropolyether component is examined, and their impact on performance by application method is discussed in this paper...

- How to Formulate "Eco-Friendly" Anticorrosive Coatings
Currently, the challenges faced by the coatings industry are not just to reduce costs and improve performance but also to fulfill strict legal requirements. The so-called "Eco-Friendly " anticorrosive coatings used to contain high or even 100% solids (like powder coatings), have low or zero VOCs. They do not contain reportable compounds, are green-label compliant (United States feature) and, in Europe, following the Directive 2004/73/CE, are non toxic for the aquatic media...

- Building Façades with an Eye for Color and the Environment
What do colors mean to us? Colors fulfill several important functions. Colors are identifiers. They help us communicate, organize ourselves at work or at home, or move around in traffic. Colors also alert us. Signal colors attract our attention to things that are important. Finally, colors speak to our senses and emotions. Colors are decorative and they create different moods...

- Green Nanotech New Buzz Word In Coatings
In 2007, environmentally conscious consumers turned to "green" products in every facet of their lives. Tips on "being green" and products to buy were everywhere - online, being reported on in broadcast news, incorporated into TV shows, and in magazines and newspapers. Home builders and suppliers began to look inward to find ways to make homes more energy efficient...

- Forming Stable Polyallophanate Powder Coatings With Excellent Weathering Stability
Polyurethane powder coatings are known for excellent properties such as weathering resistance, superior flow characteristics, high flexibility and chemical resistance. The curing of polyurethane powder coatings proceeds by reaction between an OH-functionalized polyester and an isocyanate crosslinker. Due to the high reactivity of the isocyanate groups it is necessary to use blocked isocyanate crosslinkers to prevent the premature reaction of the NCO-groups and the OH-groups of the polyester. The state-of-the-art is to use two different kinds of blocking mechanisms for PU powder coatings. In the case of externally blocked isocyanate crosslinkers, the blocking agent, e. g., ε-caprolactam, is set free at temperatures above 170 °C. On the one hand, the free blocking agent improves the flow properties of the coating but the main disadvantage is its emission during the curing process. In contrast, internally blocked uretdione crosslinkers are completely emission-free. The initial disadvantage of the high curing temperatures (>190 °C) due to the dissociation of the uretdione ring was eliminated using various catalysts that enable curing temperatures of 130 °C...

- Novel Sag Control Agents for a More Robust Paint Application Process and Reduced Telegraphing
In order to obtain glossy coatings with a high-quality appearance it is necessary that surface irregularities created during paint application or during drying/curing of the paint level out sufficiently, while sagging problems are avoided. In this paper it is shown that paint thixotropy can be very useful in increasing sag resistance, improving coating appearance and widening the application window. Thixotropy can be introduced in paints by addition of sag control agents. New Sag Control Agents (SCAs) have been developed based on chiral amines, which are very efficient (%SCA needed to obtain a given amount of sag resistance) and are also able to suppress telegraphed roughness from the substrate more than the existing SCAs...

- Cure Characteristics of Cardanol-Formaldehyde Novolac Resins in the Presence of Metallic Driers
Most phenolic resins1-4 are prepared by reacting formaldehyde with phenols, which are considered to be toxic and harmful for the environment. Now, with increasing concern for environmental protection and, due to stringent regulations to ensure the same, it has become a must for industry to find eco-friendly substitutes for all harmful materials like phenols and VOCs present in organic coating compositions. The technological developments are, therefore, focused on reducing VOCs from the coatings to meet industrial requirements. To this end, the use of cardanol, obtained from Cashew Nut Shell Liquid (CNSL), as an eco-friendly substitute for phenols is gaining importance due to the decline in supply and price fluctuation in phenolic raw materials...

- Uncle Sam Wants U.V.
For a long time, I've kept a well-measured distance from all programs involving space and the military. Probably because I am horrible at remembering acronyms. For me AOL is where I logon to get my e-mail, but at Goddard it stands for Airborne Oceanographic LIDAR, while to military brass it signals an Aircraft Operating Limitation...

- Avoiding Viscosity Loss on Tinting
Two trends are evident in architectural paints today. Waterborne, or latex, paints continue to grow in use, and today's homes are increasingly being painted with deep, vibrant colors, both inside and out. While experience has shown that the best overall balance of rheology in waterborne coatings is achieved by using non-ionic associative rheology modifiers, when such coatings are tinted with high levels of colorants they often exhibit a significant decrease in viscosity. This decreased viscosity can manifest itself in a number of ways, including low sag resistance, poor brush loading and a "thin" appearance in the can. Although a number of approaches to formulating around these issues exist, there continues to be a need for viscosity-stable rheology modifiers. A new development in HEUR thickening offers significant improvements in these performance parameters...

- Conquering Color Harmony
Meeting the demands of your customer is always challenging. Meeting the requirements of a premium car company such as BMW can be overwhelming. But apparently no challenge is too big for automotive components supplier Plastic Onmium and its team of industry experts...

- Alkyd Emulsion: A Powerful Technology for Low VOC Decorative Coating
For more than 50 years, alkyd resins supplied in white spirit have been widely used in the production of high quality decorative coatings. Recently there has been a move towards lower aromatic solvents and higher solids paints which provide the end user with potentially less harmful products and minimise the impact on the environment. With the increasingly restrictive legislation concerning VOC emissions, alkyd emulsions provide a means of maintaining the benefits of alkyd chemistry whilst replacing organic solvents with water...

- New Technology to Accurately Measure and Characterize Effect Coatings
Over the last decades new effect pigments have been constantly developed with increasingly complex color shift. New effect pigments not only change their appearance with different viewing angles but also with varying illumination conditions (e.g.: direct sunlight vs. cloudy sky). As much as uniform and consistent color is essential to achieve high quality finish, the appearance of effect coatings can no longer sufficiently be described with conventional instrumentation...

- Innovative Amine Curing Agents for Epoxy Resins
Recent advances in new amine functional curing agents have improved performance of waterborne two-package epoxy coating systems. These new amine adducts offer performance advancements along with the ability to meet low- and ultra-low VOC levels. This paper will summarize the performance of a new zero-VOC, water-soluble, amine curing agent in waterborne epoxy formulations with liquid epoxy resin at less than 50g/L VOC. We will review the performance of these new starting formulations against commercially available coatings for concrete...

- Advancements in Novel Encapsulated Light Stabilizers for Waterborne Coatings
The exterior durability of most organic coatings is highly dependent upon the use of light stabilizers. The two main stabilizer categories are ultraviolet light absorbers (UVAs) and hindered amine light stabilizers (HALS). UVA chemical classes include benzophenones, cyanoacrylates, oxanilides, benzotriazoles and triazines. Today, the latter two of these classes are by far the most commercially significant to the coatings industry due to their excellent spectral coverage, high extinction coefficients and excellent photo-permanence...

- A Success Story: High-Performance 2K Waterborne Coatings
Graffito (graffiti, plural) is a word that is simple in meaning - any design, or scribbled motto, etc., drawn on a wall or other exposed surface. Yet its simple meaning belies the incredible expense and sheer nuisance associated with its practice in today's society. In fact, graffiti has been with us since the dawn of civilization; however, in today's world and global economy graffiti has often come to mean the defacing of public buildings, transportation vehicles, or any other entity that is highly visible to the general public.

- Patent Claim Reading for Technical Personnel
Most scientists become familiar with reading and writing technical documents such as research papers and reports at an early stage in their careers. Not so with patents, where skill in reading tends to come later in a career and after direct experience of patenting product developments. Like research papers or reports, patents are also technical descriptions of products or processes, but have a unique grammar and vocabulary because their objectives for being written are not the same as a report...

- America's New Coatings Show
The first American Coatings Show and Conference was held from June 2-5 at the Charlotte Convention Center in North Carolina. According to event sponsors NPCA and Vincentz Network, this premier event was very successful. The event sponsors chose NürnbergMesse as their partner for organizing the American Coatings Show...

- Antibacterial Dry Film Protection for Interior Coatings
The need for antimicrobial products to protect water-based coatings against bacteria, yeast, fungus and algae is well established in the coatings industry. For exterior coatings, the market has responded with appropriate, cost-effective antimicrobials that dramatically expand the lifespan of the applied coating...

- Silicon-Based Technology for the Coatings Industry - An Overview
Dow Corning Corporation is a leader in developing new Silicon-Based Technologies (SBTs) that advance the coatings industry and empower formulators to offer new functionality in various applications. In the past 10 years, the number of new patents related to silicon-based materials for coatings has increased exponentially, specifically related to solving the problems traditionally addressed by SBTs, such as foam control, wetting and adhesion promotion...

- New Matting Agents for Waterborne Coatings and Varnishes
A good matte finish is often required in coatings formulations. In order to fully optimize this important parameter, Michelman has recently developed two wax dispersions: Michem® Guard 349 and Michem Guard 350. Both dispersions aid in imparting a matting effect to most aqueous coatings and varnishes, while enhancing other properties such as abrasion resistance and water repellency...

- New Coating Technology Expands Color Choices for Vinyl Building Products
Since the mid-1990s, composite materials have made substantial inroads across the building products industry in the manufacture of windows, doors, trim and siding. The unprecedented strength and resilience of these materials, and their low maintenance, has made them too good to ignore. They also offer another advantage important in today's building industry: "green" appeal. While they are produced using petrochemicals, composites may be comprised of recycled materials and, therefore, reduce the harvesting of lumber...

- Improved Dirt Pickup Resistance Critical to Future Coating Innovation
This article focuses on the chemistry of dirt pickup resistance (DPR) and outlines what steps - including research, product development and testing procedures - need to be taken to provide the proper solutions...

- UV-Inkjet OLEDs - A New Technology
Polymertronics was set up in 2006 to develop technology to produce inkjet-printable, ultra-violet (UV) curable organic light-emitting diode (OLED) fluids. OLEDs that can be printed on standard UV-inkjet equipment have many advantages. They are much quicker and cheaper to produce than standard OLEDs, they can be designed and manufactured with very short lead times, they can be printed on to a range of exotic surfaces including flexible ones, they give a much sharper image than conventional OLEDs, and they have a huge range of uses in medicine, advertising, logistics, the security industry, smart packaging and other areas. UV-curable OLEDs can also be printed with UV-curable coloured inks...

- Sustainability – The New Nano
A few years ago the coatings world was ‘nano' crazy. The term nano was everywhere. I didn't know what it really meant since there wasn't an agreed-upon definition of nano. Mostly it meant adding a little of something tiny to paint. It didn't matter if was a 5-micron particle. If it was small - it was nano. "Sustainability" has replaced nano as the hot topic. I don't really understand what "sustainability" means either...

- UV/EB Raw Materials Market
The UV ink market overall fared well in 2007, according to suppliers to the market. "We see the various segments of the energy cured ink market continuing to grow at a rate slightly greater than GDP in the both the EU and U.S. and at a generally faster rate than competitive technologies," said Harald Boner, technical marketing, pigments and additives division, Clariant. "UV inks are generally perceived as an environmentally friendly technology, which may also help drive growth...

- European Union's REACH Regulation
The EU's REACH regulation has a clear message: meet the requirements or you will not be able to produce in, export to, or market within the EU. Is your company able to meet this challenge? The new European Union chemicals regulation came into force in June 2007. The regulation is known as REACH, which stands for Registration, Evaluation, Authorization and Restriction of Chemicals. The implications of REACH for chemical and down-stream industries and for associated individual companies are significant in terms of cost, managing ongoing customer and supplier relationships, and because of its far-reaching regulatory requirements...

- UV Inks and Coatings: Considerations for Plastic Substrate
Printing on plastic is a growing and challenging market for UV-curable inks and coatings. They have been successfully used for many years, but new opportunities arise daily that remind printers and formulators how difficult achieving adhesion can be...

- Growth of UV/EB Inks Throughout Europe
Energy-curing inks are continuing to grow strongly in Europe, even though the graphics market as a whole is slowing down. The big challenge now facing the energy-curing sector is how to maintain the momentum. In Eastern Europe, sales of energy curing inks are going up at 5 to 10 percent, nearly double the level of conventional inks. Demand has been particularly high in Russia, according to industry sources...

- Radcure Coatings Market: A Growing Market
The major trends in the global coatings industry revolve around environmental concerns and the reduction of VOC emissions, reducing energy costs, improving productivity and improving performance. These four factors are driving companies across all segments of the coatings industry to look for alternative coatings technology. As a result, radiation curable coatings represent the fastest growing coatings segment because they offer numerous advantages including rapid curing process, less scrap, small footprint, less work in process, a reduction in utility usage, reduction in VOCs and improved performance...

- The Future of UV Coatings is Now!
Can you think of any organization that has had 35 consecutive years of sales growth? A few come to mind that may fit that category, but you can count them on one hand. Statistics from past RadTech International shows indicate that the UV/EB formulated product growth for the North American market is just over 7% annually...

- Diverse Applications for Crystalline Calcium Sulfonate Coating Systems in Challenging Environments
Petroleum sulfonates have evolved dramatically from their emergence as by-products of white mineral oil production to multifunctional products vital to modern industry and commerce. At the turn of the century, what we now call natural petroleum sulfonates, or their precursors (sulfonic acids) were being produced in fairly large quantities as "waste product" in the production of food grade white mineral oils. It wasn't long before the sulfonate molecule was recognized for its ability to function as a detergent and corrosion inhibitor...

- Edge-Retentive and Solvent-Free Coating Based on a Renewable Raw Material
Phenalkamine curing agents, derived from the cashew nutshell liquid, provide outstanding anti-corrosion properties to epoxy coatings. This technology allows the paint formulator to provide the marine paint industry with solvent-free and edge-retentive coatings...

- Sustainable Coatings: The Long Term View
Over the past few years, this series of technology reviews has dealt with many different aspects of coatings technology. Increasingly, it has become difficult to find subject areas of general interest which do not overlap extensively with something already discussed. To bring this series to a suitable close, I thought it would be interesting to look further ahead than usual; to consider factors and technologies which may change the face of the coatings industry in the longer term...

- Current Green Coatings Do Little to Protect the Environment
Every day within the United States new green initiatives are being proposed by politicians, celebrities and businesses. California governor Arnold Schwarzenegger is supporting hybrid cars. Musician Sheryl Crow is supporting green bathroom accessories. The Home Depot recently rolled out its Eco Options program in stores throughout the country. The company also signed an agreement with The Conversion Fund to reduce CO2 emissions. With just about everyone and every sector of the business world supporting some green cause, what is the U.S. paint industry doing to protect the environment, reduce energy consumption and global warming? Not much at all, in this author's opinion...

- Advanced Process Intensification Brings Shear Genius To Pigment Dispersion
Dispersing pigments for paints and dyes increases the surface area of the product's ingredients by dispersing the solids or reducing their particle size. Advanced reactor-based technology can be used to achieve this. The technology ensures the even distribution of energy throughout the product's ingredients to increase the surface area...

- Risk Factor: Complementary Pigment Combinations
Several pigment combinations are suitable for the formulation of green color shades. For economic reasons, "complementary pigment combinations" are often used. These are green shades that are generated by mixing yellow and blue pigments. However, these mixtures may bear significant risk in terms of weather fastness, especially when the fastness properties and the pigment concentrations are not balanced, or when the formulation contains a large portion of titanium dioxide. In combination with the effect of sunlight and weathering, all of this can lead to undesirable and unacceptable color changes in the coating...

- Nano-Sanity: A Solution to the Coatings Dilemma
Albert Einstein defined insanity as doing the same thing over and over again and expecting different results. In these times of spiraling energy costs and increasing environmental concerns, that definition might be stretched to include using the same coating techniques and expecting superior results...

- LATEST NEWS OUT OF ASIA
It is not often that one can report on change of the scale that is taking place in Asia Pacific at the moment. Once in a lifetime events are shaping the global coatings industry as never before and it is not an easy task to try to do justice to the enormity of what is happening...

- Colloidal Microcrystalline Cellulose: A Unique Suspending Agent and Stabilizer for Waterborne Coatings
Colloidal microcrystalline cellulose (MCC) has been used widely in the food and pharmaceutical industries to suspend dense particles, prevent phase separation and stabilize emulsions. This study demonstrates that colloidal MCC has the same functionalities in waterborne coatings. It significantly improves the in-can shelf stability of waterborne coatings without negatively impacting application properties...

- Measurement and Instrumentation
The earliest measuring instruments used to evaluate wet and dry coatings were the human eye and hand. Today's instruments do more, do it faster and do it better, but terms such as thumb tack, touch dry and rubout serve to remind us of the old approach. Today we take it for granted that a thickness measuring instrument will store hundreds (or thousands) of data points readily, thus saving us valuable time which can be used later in trying to make sense of statistical analyses of the data. That's no longer news - so what is? Company names are provided in this review to assist readers in identifying whether a particular technology may be of interest. This does not imply (unless it is specifically indicated) that the named companies are the only providers of any of the techniques or instruments described...

- Going Green With Akzo Nobel
Built at a cost of AUD 51 million and brimming with technical innovations, the new 10-story Melbourne City Council building - known as CH2 - has been awarded the first six star design rating from the country's Green Building Council...

- Innovative Technology
For designers, the consumers' affinity for product differentiation is driving color customization in directions never before imagined. Until recently, the cost and logistics of mass color customization made it impractical from an OEM point of view. However, new technologies, such as AURA® infusion technology, are changing the equation, making mass customization a reality. In fact, the day may be coming when home appliances are custom-colored to match room décor, or other home appliances and electronics receive a custom splash of color to brighten kitchens, family rooms, bedrooms and every other place in the house.

- CEPE Gives Direction
The CEPE welcomed some 150 company representatives from the European paint and surface coatings industry to the Cote d'Azur in France, where it held its first annual conference and annual general meeting since restructuring. The small and medium-sized companies (SMEs) came to Nice with one goal in mind: they were hoping that the CEPE would help to provide some direction in regard to their chances and prospects in the European paint and surface coatings market.

- Waterborne Coatings for Furniture
The Italian-based ICA Group, located in Civitanova Marche, Italy, is a specialist in the manufacture of wood coatings. In collaboration with Giardina Officine Aeromeccaniche, it developed coating cycles that make it possible to achieve finishes that are easily comparable to those achieved using traditional, solventborne products, but with a drastic reduction in environmental impact.

- Powder Coating
Recent Advancements for Industrial Plastics Applications

The growth of powder coatings has been dramatic during the last decade with new applications continually being developed, including plastics. Innovations in processes and materials have opened previously unimaginable opportunities. Although environmental advantages have been a strong motivating factor for the conversion of liquid coatings to powder coatings, the bottom line for many companies is increased profitability. Leading manufacturers of powder coating technology foresee untapped potential in plastics applications including automotive, appliances, and many more...

- Modern Flexible Coating Lines: Optimized for Demanding Coatings
In the last few years, there have been some significant changes in the way companies do business. Gone are the days when business strategies were laid down to produce the same product for ten years. Today, companies do not plan as far ahead. The automobile industry is a good example of this rapid product turnover. For instance, a model has a life expectancy of about five years before it is extensively "face lifted", requiring virtually all new plastic trims and bezels. To meet such everchanging situations, companies require tools that are adapted quickly to meet these new demands. A tool that can be used for only one process is a luxury few companies can afford. Likewise, coating lines are no exception. To justify their investment costs, they must meet today's demands as well as tomorrow's...

- Take a powder…
Powder coatings have evolved continuously for more than half a century (or much longer if we include cosmetic applications). The original system in which thermoplastic polyamide or vinyl powders are applied by fluidised bed is now reduced to a niche product in a market dominated by spray-applied thermoset powders, with radiation-curing also occupying a significant market position...

- 'Smart' Inks and Coatings: An Alternative to Traditional Printing Methods
Over the past few decades, the printing industry has undergone a number of developments to existing techniques such as ink-jet and laser printing. Developments have focused on improvements to existing techniques rather than completely new innovations. The last few years have also seen the introduction of "smart" technologies, ones that have intelligent features - for example color-changing inks and coatings, which are active rather than passive techniques. One company has developed an award-winning, "smart" process that looks set to revolutionize the printing industry - DataLase®. This article will review traditional printing techniques and the technology that has emerged as a viable alternative.

- Interviews with Industry Leaders
This is the beginning of a new series featuring interviews with the global leaders of major paint companies and their suppliers focusing on innovation and trends in the coatings market. We also include some facts about the market in which the company operates and a short profile of its business. In the first of the series we are very pleased to welcome Dr Joachim Wolff of Bayer MaterialScience who talks to SpecialChem about Polyurethanes...

- UV Coating - Overprintability and Adhesion Phenomena
PART II: Description of 4 Adhesion Phenomena
Recommendations of Raw material Suppliers and Conclusion

This is the second part of our article dedicated to UV-Coating and overprintability, in this part we present four other adhesion phenomena and recommendations of raw material suppliers for the design of overprintable varnishes. The conclusion gives a summary of the most important features leading to a set of criteria for the development of overprintable and glueable varnishes...

- Thinking outside the mould: coatings for plastics
Although (as shown below) there are a vast number of polymers that are collectively known as 'plastics', the majority have common features which make coating difficult. This article reviews some of the applications, problems and ever-improving range of solutions associated with the coating of plastics. A number of issues which are relevant, such as printing of food packaging have been discussed in previous articles and will not be repeated here...

- Small Bead Milling Process Optimization
The development of products is usually conducted on laboratory scale equipment that is similar to that used in the plant. Once the customer accepts the sample, the last formula made is given to the plant to produce. This formulation is transferred to the plant with varying degrees of detail. The product is scheduled for production usually as single batch...

- Coatings: Powder on Plastics
Innovations in processes and materials open a new realm

When considering coating plastics, the first obvious question pops up. Why bother? By simply using pigmented resin one gets a molded-in color that can't scratch off and one that also eliminates the need for a finishing operation. The answer is two-fold. One is that, in thick, large plastic parts, it can be more economical to put color on the outside where it is needed, instead of throughout the entire thickness of the part. The other is better color matching. Everyone has had the experience of seeing an assembly of metal and plastic parts that didn't perfectly match, and where the fading on the plastic only made the color mismatch worse over time...

- The Effect of Surfactant Selection on Emulsion Polymer Properties
The emulsion polymerization process has been discussed in a number of publications. The primary role of surfactants in emulsion polymerization is to lower the interfacial tension, which allows the emulsification of reactive vinyl monomers and the formation of stable colloidal dispersions of nano-size polymer particles. Conventional surfactants aid in the emulsification of monomers inside the micelles, stabilize the polymer particles during nucleation and growth and promote the stability of the resulting latex...

- UV Stabilization of Waterborne Coatings
Besides high efficiency, UV stabilizers have to meet some other basic, but most important requirements. To grant such high efficiency, perfect compatibility, that is excellent solubility in the film-forming binder, is a definite must. This requires high permanence and low volatility as well, especially with stoving enamels. These properties must be present along with no negative side effects such as color contribution, interaction with other paint elements or influence on crosslinking...

- UV Coating - Overprintability and Adhesion
Part I: Introduction and Description of 4 Adhesion Phenomena

The Overprintability of UV-Coating and Inks is an important issue in the area of packaging and labeling, such applications like, ink printing, hot foil stamping, thermal transfer printing and glue-ability are concerned...

- Process Improvement and Six Sigma
The improvement process adventure starts when your manager walks in and says "we need to - fix the product, increase the yield of, and reduce the cost of. The time table for achieving the assignment is usually now or sooner. If you're lucky you have until the staff meeting on Friday...

- Freeing the environment
The quest to produce environmentally friendly and low-toxicity coatings has generated many new types of coatings and modifications to existing systems...

- Advantages of Multi-Speed Viscosity Testing for Coatings
Coatings manufacturers use various methods for quality assurance/quality control or QA/QC. The devices are simple and low-cost. Data usually consists of one point, giving what essentially is a "go/no-go" test...

- High-Solids Alkyd Strategy
This article presents new possible approaches for alkyd resin architecture in order to comply with market constraints related to VOC emissions. Examples and performance of alkyd concepts are presented with regard to VOC content and performance for "interior/exterior trim and cladding paints for wood and metal"...

- R&H Enhancing Roadway Safety
It has been nearly 100 years since large-scale, production-line manufacturing made automobiles affordable for average Americans-and we haven't looked back since...

- As good as new: automotive refinishes
If your car is damaged, you hope that (among other things) the bodyshop will be able to match both the appearance and the durability of the original finish on the repaired areas of bodywork...

- Accept no (l)imitations: the evolving technologies of security printing
One of the unfortunate consequences of the digital revolution has been the greater ease with which all kinds of printed matter and manufactured goods can be counterfeited, and the greater speed with which international criminal activities can be organised...

- Walk this way: floor coating technologies
The term 'floor coatings' covers many technologies and applications whose main common property is a requirement for a hard-wearing, abrasion and scuff resistant surface. The primary types of floor which can or must be protected by surface coatings are wood, concrete and PVC (vinyl), though reference will be made to other substrates below...

- Paint products: Accelerated stability and quality testing
Part I: Direct measurement of separation and segregation by multisample analytical centrifugation

These stability issues have to be addressed not only during development of new paint products but also for quality assurance during production on a regular basis...

- Waterborne Polyurethane Coatings for Wood Floors – The Next Generation
New pathways were explored to make aqueous polyurethane dispersions without the co-solvent nmethylpyrolidone (NMP). This includes methods to process these materials with alternate cosolvents as well as with co-solvents that can be removed from the product during processing...

- Acrylic Hybrid technology
To design higher performance surface coatings, coating formulators must choose from myriad polymer chemistries. Hybrid polymer technology combines the advantages of one polymer species with another - while offsetting their shortcomings - in a synergistic manner to create a higher performance class of polymers. This article discusses the acrylic hybrid technology and its applications, particularly in the design and development of non-yellowing, high performance coatings...

- Waterborne technology: its greatest limitation is your imagination
Waterborne paints have a long and successful history in certain niche applications (see this month's editorial), but the twin issues of environmental legislation and the low cost of water as a solvent have encouraged their much wider use...

- Skin-deep Beauty of Automotive Coatings
Most car of us have a special "love relationship" with our cars - much is to do with their aesthetic appearance. Shape, colour and surfaces contribute to a car's attraction in the show-room...

- Coating Film Defects: backgrounds and how to prevent them
Film defects can ruin protective and aesthetical properties of coatings. A huge amount of time and money is invested in preventing and resolving them...

- Smaller, greener, cleaner: production technology changes direction
Not too long ago, coatings and their raw materials were produced by a limited range of long-established production methods. But in recent years new technologies have been studied and commercialised which are not merely significant improvements on the old established methods, but exemplify different ways of thinking about manufacture...

- Precision polymers
Coatings have traditionally been based on 'random' polymers, varying statistically in their molecular weight, degree of branching, and in the case of copolymers, the ratio between the different components...

- Use of Inherently Conductive Polymers in Coatings & Inks
Definition of Conductivity
Conductivity is the measure of how well a material accommodates the transport of electric charge (conducts an electric current)...

- Matching the market: new ways to sell paint
As observed in last month's Frontiers article, we usually buy paint either to protect substrates or to change their appearance. But it is also relevant to ask why we buy a particular brand or type of paint...

- New product development in coatings and inks: how does physical chemistry fit in?
Global coating and ink markets are in an innovative mood. The innovations are driven by environment, health, safety, quality improvement and cost reduction. Especially the regulations with respect to Volatile Organic Components (VOC) challenge companies to find solutions in waterbased, high-solids and solvent-free systems...

- Photointiators Part 3: What’s New or May Be Coming?
Parts 1 and 2 of this series dealt with the chemistries of photoinitiators and formulations of UV cured systems containing such photoinitiators...

- Keeping in touch: the technology and applications of tactile coatings

- Nanowars: hygienic coatings fight dirt and disease
We spend our lives surrounded by bacteria, fungi, algae viruses and other forms of microscopic life. Microbes comprise 80-90% of the Earth’s total biomass, and even under 'clean' conditions we may inhale several thousand fungal spores per day...

- The Principles of Dispersion and Stabilization of Pigments
Product developers experience that the dispersion and stabilisation of pigments and fillers in modern coatings and inks, like water-based, high-solids and powder coatings, is more challenging than in conventional solventbased systems...

- Photoinitiators for Coatings Applications
Part 2 - Which Photoiniator to choose?

The vast majority of the commercially available UV coating systems are based on free radical curing systems. A minority employ ionic curing processes but these will be left for a later article...

- Frontiers of coatings technology: Painting the sky
Coatings for today's ordinary commercial aircraft must cope with extreme service conditions. They may take off from searing desert heat, climb within minutes to a height of ten kilometres where temperatures fall to -55°C and where UV exposure includes high levels of short-wavelength UV (UVB), most of which is blocked by the atmosphere at ground level...

- DMSO®-based paint strippers
DMSO-based formulations have been designed to substitute methylene-chloride based, classical strippers. Unexpected synergy effects have been obtained with ethers, giving efficiencies comparable to methylene chloride-methanol systems...

- Smart coatings: communications out of a can
The term 'smart coatings', like 'nanotechnology' and many other fashionable technological terms, has no clear and recognised definition...

- HSE review: September 2006
The second issue of this quarterly column highlights a number of conflicts in the way that HSE issues are interpreted. Some of this is all too familiar - as in the case of the REACH update - but some is unexpected and provides food for thought...

- Off-Diagonal Effects of Alkanolamines in Waterborne Coatings
Alkanolamines are ideal pH-neutralizing agents in a number of ways, including compatibility with latex emulsions, solubility in latex emulsions, a sufficiently high pKa value to allow for efficient neutralization to pH values between 8 and 10, and intermediate vapor pressures that allow for evaporation at a controlled rate. The optimum alkanolamine for a given coating formulation will be the one with the best balance of physical properties, allowing for the maximum number of benefits and the minimum number of negative side effects (e.g., odor)...

- Photoinitiators for Coatings Applications
Part 1 – A brief overview

Conventional thermoset coating formulations are thermally cured through crosslinking and polymerisation processes. Catalysts are often added to such formulations to initiate these curing processes...

- Painting without paint
We are all familiar with the use of self-adhesive decals on road and rail vehicles, which have almost entirely replaced traditional sign-writing with a brush and can of paint. Self-adhesive films are also often used to provide temporary protection to everything from the screen of a mobile phone up to complete vehicles being transported from factory to showroom....

- Flame Retardants for Coatings - a Growing Need?
Much effort has been made to incorporate flame retardants in plastics and textiles. Deaths due to fires have dropped significantly since their introduction as flame retardant materials delay the onset of fires thus allowing potential victims more time to escape...

- Ipex: a world tour of the printing industry
Every four years, Ipex draws together the world's printing industry at Birmingham's NEC. Like Germany's Drupa, it is a huge exhibition which showcases the entire spectrum of printing technology, from DTP software through to packaging and labelling machinery...

- The photochemistry of semiconductor nano-particles
The photochemical aspects of semiconductor nano-particles are of outmost importance for the qualities and the behavior of many coatings. Only the combination of these words is not so often used to describe the numerous coatings whose behaviour , intentionally or not, depends on the photochemical properties of the semiconductor particles they contain...

- “Smart” Uses of Inkjet Printing
In the early 1980's I had the privilege to visit the leading inkjet printing companies in Japan and the USA. These were the early days when dyes were still being developed for the newly commercial printers. I am still amazed as I read of the growth explosion of inkjet printers for computers, textile printing and graphic arts and yet this list of applications is far from complete.

- Shrink-fit solutions: Applications of Nanotech in Coatings
Nanotechnology, the development of the minute, is already making its mark in the coatings industry, with a number of commercial applications offering benefits such as greatly improved scratch resistance in automotive finishes, antibacterial properties, self-cleaning finishes and enhanced weathering resistance. And we've only just started to exploit this more refined approach to coatings chemistry.

- Functional Coatings
The title of engineer has found its way into any number of job descriptions in virtually every field. The list doesn’t end with Sanitary Engineers, Traffic Engineers or Culinary Engineers but continues on to include most professions, whether technically orientated or not. As such, the world’s Coil Coaters and others who apply a coating to a metallic surface should probably be called Surface Engineers.

- Industrial Coatings – How Much is Durability an Issue!
Industrial Coatings in this article cover both the automotive and general industrial markets.



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